Antagonism between extreme negative linear compression and spin crossover in [Fe(dpp)(2) (NCS)(2) ]⋅py.
SHEPHERD, Helena
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de chimie de coordination [LCC]
See more >
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de chimie de coordination [LCC]
SHEPHERD, Helena
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de chimie de coordination [LCC]
< Reduce
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de chimie de coordination [LCC]
Language
en
Article de revue
This item was published in
Angewandte Chemie International Edition. 2012, vol. 51, n° 16, p. 3910-3914
Wiley-VCH Verlag
English Abstract
A scissor-like geometric mechanism is responsible for the strongest negative linear compression effect yet observed in a molecular material, [Fe(dpp)(2) (NCS)(2) ]⋅py (see picture; dpp=dipyrido[3,2-a:2'3'-c]phenazine), ...Read more >
A scissor-like geometric mechanism is responsible for the strongest negative linear compression effect yet observed in a molecular material, [Fe(dpp)(2) (NCS)(2) ]⋅py (see picture; dpp=dipyrido[3,2-a:2'3'-c]phenazine), C gray, N blue, S yellow, Fe red). The same mechanism is also responsible for suppressing the high-spin to low-spin transition under pressure.Read less <
English Keywords
Iron
Mechanical properties
Molecular materials
N ligands
Spin crossover
Origin
Hal imported