Antagonism between extreme negative linear compression and spin crossover in [Fe(dpp)(2) (NCS)(2) ]⋅py.
Langue
en
Article de revue
Ce document a été publié dans
Angewandte Chemie International Edition. 2012, vol. 51, n° 16, p. 3910-3914
Wiley-VCH Verlag
Résumé en anglais
A scissor-like geometric mechanism is responsible for the strongest negative linear compression effect yet observed in a molecular material, [Fe(dpp)(2) (NCS)(2) ]⋅py (see picture; dpp=dipyrido[3,2-a:2'3'-c]phenazine), ...Lire la suite >
Mots clés en anglais
Iron
Mechanical properties
Molecular materials
N ligands
Spin crossover