Antagonism between extreme negative linear compression and spin crossover in [Fe(dpp)(2) (NCS)(2) ]⋅py.
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en
Article de revue
Este ítem está publicado en
Angewandte Chemie International Edition. 2012, vol. 51, n° 16, p. 3910-3914
Wiley-VCH Verlag
Resumen en inglés
A scissor-like geometric mechanism is responsible for the strongest negative linear compression effect yet observed in a molecular material, [Fe(dpp)(2) (NCS)(2) ]⋅py (see picture; dpp=dipyrido[3,2-a:2'3'-c]phenazine), ...Leer más >
Palabras clave en inglés
Iron
Mechanical properties
Molecular materials
N ligands
Spin crossover