Investigation of the reaction between benzophenone and trimethylaluminium: A source of novel aluminic activator for single-site olefin polymerization catalysts
CRAMAIL, Henri
Laboratoire de Chimie des polymères organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des polymères organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
CRAMAIL, Henri
Laboratoire de Chimie des polymères organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
< Reduce
Laboratoire de Chimie des polymères organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Language
en
Article de revue
This item was published in
Macromolecular Symposia. 2006, vol. 231, p. 110-115
Wiley-VCH Verlag
English Abstract
The reaction between benzophenone and TMA was investigated in details at 20 degrees C for different TMA/benzophenone (r) ratios. For r = 2, a heterodimer mu-(1,1-diphenylethoxy)-mu-methyl-tetramethyldialuminium (B) is only ...Read more >
The reaction between benzophenone and TMA was investigated in details at 20 degrees C for different TMA/benzophenone (r) ratios. For r = 2, a heterodimer mu-(1,1-diphenylethoxy)-mu-methyl-tetramethyldialuminium (B) is only formed. The latter was found able to activate MeDIP(2,6-iPrPh)(2)FeCl2 catalyst towards ethylene polymerization. Such catalytic system leads to the formation of high molar mass polyethylene with a broad molar mass distribution, without the presence of oligomers, that is attributed to a strong reduction of the transfer reaction to TMARead less <
English Keywords
polyethylene (PE)
MAO
benzophenone
catalysts
iron catalyst
Origin
Hal imported