Investigation of the reaction between benzophenone and trimethylaluminium: A source of novel aluminic activator for single-site olefin polymerization catalysts
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | DALET, Thomas | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 2 LCPO : Biopolymers & Bio-sourced Polymers | |
| dc.contributor.author | CRAMAIL, Henri | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | DEFFIEUX, Alain | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2006 | |
| dc.identifier.issn | 1022-1360 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20662 | |
| dc.description.abstractEn | The reaction between benzophenone and TMA was investigated in details at 20 degrees C for different TMA/benzophenone (r) ratios. For r = 2, a heterodimer mu-(1,1-diphenylethoxy)-mu-methyl-tetramethyldialuminium (B) is only formed. The latter was found able to activate MeDIP(2,6-iPrPh)(2)FeCl2 catalyst towards ethylene polymerization. Such catalytic system leads to the formation of high molar mass polyethylene with a broad molar mass distribution, without the presence of oligomers, that is attributed to a strong reduction of the transfer reaction to TMA | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | polyethylene (PE) | |
| dc.subject.en | MAO | |
| dc.subject.en | benzophenone | |
| dc.subject.en | catalysts | |
| dc.subject.en | iron catalyst | |
| dc.title.en | Investigation of the reaction between benzophenone and trimethylaluminium: A source of novel aluminic activator for single-site olefin polymerization catalysts | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/masy.200551312 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Macromolecular Symposia | |
| bordeaux.page | 110-115 | |
| bordeaux.volume | 231 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00395729 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00395729v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Macromolecular%20Symposia&rft.date=2006&rft.volume=231&rft.spage=110-115&rft.epage=110-115&rft.eissn=1022-1360&rft.issn=1022-1360&rft.au=DALET,%20Thomas&CRAMAIL,%20Henri&DEFFIEUX,%20Alain&rft.genre=article |
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