N-Acetoxy-phthalimide (NAPI) as a new H-abstracting agent at high temperature: application to the melt functionalization of polyethylene
FLAT, Jean-Jacques
Centre de recherche, développement, applications et technique de l'ouest [CERDATO]
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Centre de recherche, développement, applications et technique de l'ouest [CERDATO]
FLAT, Jean-Jacques
Centre de recherche, développement, applications et technique de l'ouest [CERDATO]
< Reduce
Centre de recherche, développement, applications et technique de l'ouest [CERDATO]
Language
en
Article de revue
This item was published in
Polymer Chemistry. 2013, vol. 4, p. 2676-2679
Royal Society of Chemistry - RSC
English Abstract
A new H-abstracting agent, N-acetoxy-phthalimide (NAPI), was designed that cleaves mainly homolytically into acyloxyl and aminyl radicals at 190 degrees C. Melt PE grafting experiments confirmed the H-abstraction efficiency ...Read more >
A new H-abstracting agent, N-acetoxy-phthalimide (NAPI), was designed that cleaves mainly homolytically into acyloxyl and aminyl radicals at 190 degrees C. Melt PE grafting experiments confirmed the H-abstraction efficiency of NAPI. It was also shown that the grafting of maleic anhydride increased and at the same time undesired crosslinking lowered compared to peroxides.Read less <
English Keywords
BOND-DISSOCIATION ENERGIES
MALEIC-ANHYDRIDE
RADICALS
POLYMERIZATION
SELECTIVITY
ACID
Origin
Hal imported