N-Acetoxy-phthalimide (NAPI) as a new H-abstracting agent at high temperature: application to the melt functionalization of polyethylene
dc.rights.license | open | |
hal.structure.identifier | Ingénierie des Matériaux Polymères [IMP] | |
dc.contributor.author | BELEKIAN, Denis | |
hal.structure.identifier | Ingénierie des Matériaux Polymères [IMP] | |
dc.contributor.author | CASSAGNAU, Philippe | |
hal.structure.identifier | Centre de recherche, développement, applications et technique de l'ouest [CERDATO] | |
dc.contributor.author | FLAT, Jean-Jacques | |
hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
dc.contributor.author | QUINEBÈCHE, Sébastien | |
dc.contributor.author | AUTISSIER, Laurent | |
hal.structure.identifier | Institut de Chimie Radicalaire [ICR] | |
dc.contributor.author | BERTIN, Denis | |
dc.contributor.author | SIRI, Didier | |
hal.structure.identifier | Institut de Chimie Radicalaire [ICR] | |
dc.contributor.author | GIGMES, Didier | |
hal.structure.identifier | Institut de Chimie Radicalaire [ICR] | |
dc.contributor.author | GUILLANEUF, Yohann | |
hal.structure.identifier | Ingénierie des Matériaux Polymères [IMP] | |
dc.contributor.author | CHAUMONT, Philippe | |
hal.structure.identifier | Ingénierie des Matériaux Polymères [IMP] | |
dc.contributor.author | BEYOU, Emmanuel | |
dc.date.accessioned | 2020 | |
dc.date.available | 2020 | |
dc.date.issued | 2013 | |
dc.identifier.issn | 1759-9954 | |
dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20408 | |
dc.description.abstractEn | A new H-abstracting agent, N-acetoxy-phthalimide (NAPI), was designed that cleaves mainly homolytically into acyloxyl and aminyl radicals at 190 degrees C. Melt PE grafting experiments confirmed the H-abstraction efficiency of NAPI. It was also shown that the grafting of maleic anhydride increased and at the same time undesired crosslinking lowered compared to peroxides. | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry - RSC | |
dc.subject.en | BOND-DISSOCIATION ENERGIES | |
dc.subject.en | MALEIC-ANHYDRIDE | |
dc.subject.en | RADICALS | |
dc.subject.en | POLYMERIZATION | |
dc.subject.en | SELECTIVITY | |
dc.subject.en | ACID | |
dc.title.en | N-Acetoxy-phthalimide (NAPI) as a new H-abstracting agent at high temperature: application to the melt functionalization of polyethylene | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/c3py00246b | |
dc.subject.hal | Chimie/Polymères | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Polymer Chemistry | |
bordeaux.page | 2676-2679 | |
bordeaux.volume | 4 | |
bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
bordeaux.institution | Bordeaux INP | |
bordeaux.institution | Université de Bordeaux | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00870517 | |
hal.version | 1 | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00870517v1 | |
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