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Optimizing the stability of trapped metastable spin states
Language
en
Chapitre d'ouvrage
This item was published in
Spin-crossover materials : properties and applications, Spin-crossover materials : properties and applications. 2013p. 475-506
Wiley
English Abstract
In the domain of transition metal complexes, there are several possibilities for generating light-induced switches accompanied by drastic modifications of magnetic, volume and/or optical properties.1-4 Among the best known ...Read more >
In the domain of transition metal complexes, there are several possibilities for generating light-induced switches accompanied by drastic modifications of magnetic, volume and/or optical properties.1-4 Among the best known and extensively studied systems, we can cite metal-centered thermal spin-transition (observed in iron(II) SCO materials), valence tautomerism (catecholate complexes of Co(II)), metal-to-metal charge transfer (Prussian Blue analogs), metal-to-ligand charge transfer (nitroprusside complexes), and finally, ail ligand modifications that induce a change of spin state, such as isomerization (stilbenoid complexes) and open/close (diarylethene type ligands) processes...Read less <
Origin
Hal imported