LÉTARD, Jean; CHASTANET, Guillaume; DESPLANCHES, Cédric; GUIONNEAU, Philippe

doi:10.1002/9781118519301.ch19

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LÉTARD, Jean
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

CHASTANET, Guillaume
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

DESPLANCHES, Cédric
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

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Spin-crossover materials : properties and applications, Spin-crossover materials : properties and applications. 2013p. 475-506

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In the domain of transition metal complexes, there are several possibilities for generating light-induced switches accompanied by drastic modifications of magnetic, volume and/or optical properties.1-4 Among the best known and extensively studied systems, we can cite metal-centered thermal spin-transition (observed in iron(II) SCO materials), valence tautomerism (catecholate complexes of Co(II)), metal-to-metal charge transfer (Prussian Blue analogs), metal-to-ligand charge transfer (nitroprusside complexes), and finally, ail ligand modifications that induce a change of spin state, such as isomerization (stilbenoid complexes) and open/close (diarylethene type ligands) processes...< Leer menos

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Optimizing the stability of trapped metastable spin states

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