Substrate-dependent spin crossover in an Fe( ii ) scorpionate complex
MARTINEZ, Edoardo
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
SERRANO, Giulia
Dipartimento di Ingegneria Industriale [DIEF]
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
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Dipartimento di Ingegneria Industriale [DIEF]
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
MARTINEZ, Edoardo
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
SERRANO, Giulia
Dipartimento di Ingegneria Industriale [DIEF]
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
Dipartimento di Ingegneria Industriale [DIEF]
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
CORTIGIANI, Brunetto
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
SQUILLANTINI, Lorenzo
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
MANNINI, Matteo
Department of Chemistry ''Ugo Schiff"
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
Department of Chemistry ''Ugo Schiff"
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
POGGINI, Lorenzo
Istituto di Chimica dei Composti Organometallici [ICCOM]
Department of Chemistry ''Ugo Schiff"
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
< Reduce
Istituto di Chimica dei Composti Organometallici [ICCOM]
Department of Chemistry ''Ugo Schiff"
National Interuniversity Consortium of Materials Science and Technology [INSTM ]
Language
en
Article de revue
This item was published in
Journal of Materials Chemistry C. 2023, vol. 11, n° 34, p. 11518-11528
Royal Society of Chemistry
English Abstract
A new spin-crossover complex based on a heteroscorpionate ligand was synthesized and characterized. Thin films were grown by sublimation in an ultra-high vacuum on highly oriented pyrolytic graphite (HOPG) and on single ...Read more >
A new spin-crossover complex based on a heteroscorpionate ligand was synthesized and characterized. Thin films were grown by sublimation in an ultra-high vacuum on highly oriented pyrolytic graphite (HOPG) and on single crystal Au (111), and spectroscopically characterized using X-ray absorption and X-ray photoemission. Temperature-dependent experiments on sub-nanometric deposits demonstrated that the thermally induced spin-crossover is preserved at a sub-monolayer (0.7 ML) coverage on HOPG, while films with similar thickness lose the switching behaviour when deposited on a Au(111) surface. The system was unresponsive to light stimuli at low temperatures independently of the used substrate.Read less <
ANR Project
Initiative d'excellence de l'Université de Bordeaux
Origin
Hal imported