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Substrate-dependent spin crossover in an Fe( ii ) scorpionate complex

hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPÉNICAUD, Margaux
hal.structure.identifierDepartment of Chemistry “Ugo Schiff”
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
dc.contributor.authorMARTINEZ, Edoardo
hal.structure.identifierDipartimento di Ingegneria Industriale [DIEF]
hal.structure.identifierDepartment of Chemistry “Ugo Schiff”
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
dc.contributor.authorSERRANO, Giulia
hal.structure.identifierDepartment of Chemistry “Ugo Schiff”
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
dc.contributor.authorCORTIGIANI, Brunetto
hal.structure.identifierDepartment of Chemistry “Ugo Schiff”
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
dc.contributor.authorSQUILLANTINI, Lorenzo
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGONZÁLEZ-ESTEFAN, Juan
hal.structure.identifierEuropean Synchrotron Radiation Facility [Grenoble] [ESRF]
dc.contributor.authorVELEZ-FORT, Emilio
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDUTTINE, Mathieu
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGONIDEC, Mathieu
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorROSA, Patrick
hal.structure.identifierDepartment of Chemistry ''Ugo Schiff"
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
dc.contributor.authorMANNINI, Matteo
hal.structure.identifierIstituto di Chimica dei Composti Organometallici [ICCOM]
hal.structure.identifierDepartment of Chemistry ''Ugo Schiff"
hal.structure.identifierNational Interuniversity Consortium of Materials Science and Technology [INSTM ]
dc.contributor.authorPOGGINI, Lorenzo
dc.date.issued2023
dc.identifier.issn2050-7526
dc.description.abstractEnA new spin-crossover complex based on a heteroscorpionate ligand was synthesized and characterized. Thin films were grown by sublimation in an ultra-high vacuum on highly oriented pyrolytic graphite (HOPG) and on single crystal Au (111), and spectroscopically characterized using X-ray absorption and X-ray photoemission. Temperature-dependent experiments on sub-nanometric deposits demonstrated that the thermally induced spin-crossover is preserved at a sub-monolayer (0.7 ML) coverage on HOPG, while films with similar thickness lose the switching behaviour when deposited on a Au(111) surface. The system was unresponsive to light stimuli at low temperatures independently of the used substrate.
dc.description.sponsorshipInitiative d'excellence de l'Université de Bordeaux
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.title.enSubstrate-dependent spin crossover in an Fe( ii ) scorpionate complex
dc.typeArticle de revue
dc.identifier.doi10.1039/D3TC01620J
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Materials Chemistry C
bordeaux.page11518-11528
bordeaux.volume11
bordeaux.issue34
bordeaux.peerReviewedoui
hal.identifierhal-04185444
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-04185444v1
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