PÉNICAUD, Margaux; MARTINEZ, Edoardo; SERRANO, Giulia; CORTIGIANI, Brunetto; SQUILLANTINI, Lorenzo; GONZÁLEZ-ESTEFAN, Juan; VELEZ-FORT, Emilio; DUTTINE, Mathieu; GONIDEC, Mathieu; ROSA, Patrick; MANNINI, Matteo; POGGINI, Lorenzo

doi:10.1039/D3TC01620J

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PÉNICAUD, Margaux
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

MARTINEZ, Edoardo
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]

SERRANO, Giulia
Dipartimento di Ingegneria Industriale [DIEF]
Department of Chemistry “Ugo Schiff”
National Interuniversity Consortium of Materials Science and Technology [INSTM ]

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Article de revue

Ce document a été publié dans

Journal of Materials Chemistry C. 2023, vol. 11, n° 34, p. 11518-11528

Royal Society of Chemistry

Résumé en anglais

A new spin-crossover complex based on a heteroscorpionate ligand was synthesized and characterized. Thin films were grown by sublimation in an ultra-high vacuum on highly oriented pyrolytic graphite (HOPG) and on single crystal Au (111), and spectroscopically characterized using X-ray absorption and X-ray photoemission. Temperature-dependent experiments on sub-nanometric deposits demonstrated that the thermally induced spin-crossover is preserved at a sub-monolayer (0.7 ML) coverage on HOPG, while films with similar thickness lose the switching behaviour when deposited on a Au(111) surface. The system was unresponsive to light stimuli at low temperatures independently of the used substrate.< Réduire

DOI

http://dx.doi.org/10.1039/D3TC01620J

Project ANR

Initiative d'excellence de l'Université de Bordeaux - ANR-10-IDEX-0003

Origine

Importé de hal

Unités de recherche

Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB) - UMR 5026