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High performance optical oxygen sensors based on iridium complexes exhibiting interchromophore energy shuttling
Language
en
Article de revue
This item was published in
Analyst. 2016, vol. 141, n° 10, p. 3090-3097
Royal Society of Chemistry
English Abstract
A doubly pyrene-grafted bis-cyclometallated iridium complex with engineered electronically excited states demonstrates reversible electronic energy transfer between adjacent chromophores giving rise to extremely long-lived ...Read more >
A doubly pyrene-grafted bis-cyclometallated iridium complex with engineered electronically excited states demonstrates reversible electronic energy transfer between adjacent chromophores giving rise to extremely long-lived red luminescence in solution (τ = 480 μs). Time-resolved spectroscopic studies afforded determination of pertinent photophysical parameters including rates of energy transfer and energy distribution between constituent chromophores in the equilibrated excited molecule (ca. 98% on the organic chromophores). Incorporation into a nanostructured metal–oxide matrix (AP200/19) gave highly sensitive O 2 sensing films, as the detection sensitivity was 200–300% higher than with the commonly used PtTFPP and approaches the sensitivity of the best O 2-sensing dyes reported to date.Read less <
European Project
Tris-heteroleptic cyclometalated iridium(III) complexes for white electroluminescence
ANR Project
Architectures à base de foldamères pour le transport d'electrons - ANR-12-BS08-0007
Origin
Hal imported
