Afficher la notice abrégée

High performance optical oxygen sensors based on iridium complexes exhibiting interchromophore energy shuttling

hal.structure.identifierDepartment of Analytical Chemistry, Granada
dc.contributor.authorMEDINA-RODRÍGUEZ, Santiago
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorDENISOV, Sergey A.
hal.structure.identifierSchool of Chemistry [Birmingham]
dc.contributor.authorCUDRÉ, Yanouk
hal.structure.identifierSchool of Chemistry [Birmingham]
dc.contributor.authorMALE, Louise
hal.structure.identifierDepartment of Analytical Chemistry, Granada
dc.contributor.authorMARÍN-SUÁREZ, Marta
hal.structure.identifierDepartment of Analytical Chemistry, Granada
dc.contributor.authorFERNÁNDEZ-GUTIÉRREZ, Alberto
hal.structure.identifierDepartment of Analytical Chemistry, Granada
dc.contributor.authorFERNÁNDEZ-SÁNCHEZ, Jorge F.
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorTRON, Arnaud
hal.structure.identifierLaboratoire Ondes et Matière d'Aquitaine [LOMA]
dc.contributor.authorJONUSAUSKAS, Gediminas
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorMCCLENAGHAN, Nathan D.
hal.structure.identifierSchool of Chemistry [Birmingham]
dc.contributor.authorBARANOFF, Etienne
dc.date.created2016-02-19
dc.date.issued2016
dc.identifier.issn0003-2654
dc.description.abstractEnA doubly pyrene-grafted bis-cyclometallated iridium complex with engineered electronically excited states demonstrates reversible electronic energy transfer between adjacent chromophores giving rise to extremely long-lived red luminescence in solution (τ = 480 μs). Time-resolved spectroscopic studies afforded determination of pertinent photophysical parameters including rates of energy transfer and energy distribution between constituent chromophores in the equilibrated excited molecule (ca. 98% on the organic chromophores). Incorporation into a nanostructured metal–oxide matrix (AP200/19) gave highly sensitive O 2 sensing films, as the detection sensitivity was 200–300% higher than with the commonly used PtTFPP and approaches the sensitivity of the best O 2-sensing dyes reported to date.
dc.description.sponsorshipArchitectures à base de foldamères pour le transport d'electrons - ANR-12-BS08-0007
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.rights.urihttp://creativecommons.org/licenses/by/
dc.title.enHigh performance optical oxygen sensors based on iridium complexes exhibiting interchromophore energy shuttling
dc.typeArticle de revue
dc.identifier.doi10.1039/c6an00497k
dc.subject.halChimie/Chimie analytique
dc.subject.halChimie/Chimie théorique et/ou physique
dc.description.sponsorshipEuropeTris-heteroleptic cyclometalated iridium(III) complexes for white electroluminescence
bordeaux.journalAnalyst
bordeaux.page3090-3097
bordeaux.volume141
bordeaux.issue10
bordeaux.peerReviewedoui
hal.identifierhal-01349284
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01349284v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Analyst&rft.date=2016&rft.volume=141&rft.issue=10&rft.spage=3090-3097&rft.epage=3090-3097&rft.eissn=0003-2654&rft.issn=0003-2654&rft.au=MEDINA-RODR%C3%8DGUEZ,%20Santiago&DENISOV,%20Sergey%20A.&CUDR%C3%89,%20Yanouk&MALE,%20Louise&MAR%C3%8DN-SU%C3%81REZ,%20Marta&rft.genre=article


Fichier(s) constituant ce document

FichiersTailleFormatVue

Il n'y a pas de fichiers associés à ce document.

Ce document figure dans la(les) collection(s) suivante(s)

Afficher la notice abrégée