2,2'-Dipyridylamino-based ligands with substituted alkyl chain groups and their mononuclear-Mn(II) spin crossover complexes
Language
en
Article de revue
This item was published in
Journal of Materials Chemistry C. 2015, vol. 3, n° 30, p. 7845-7857
Royal Society of Chemistry
English Abstract
Four new alkyl chain appended dipyridylamino-substituted-s-triazine ligands have been incorporated into seven new, mononuclear MII compounds of type [MII(NCX)2(L)2] (where NCX = NCS− or NCSe− and MII = Fe or Co). These ...Read more >
Four new alkyl chain appended dipyridylamino-substituted-s-triazine ligands have been incorporated into seven new, mononuclear MII compounds of type [MII(NCX)2(L)2] (where NCX = NCS− or NCSe− and MII = Fe or Co). These complexes have been structurally and magnetically characterised. The magnetic consequence of varying the alkyl chain length has been investigated in terms of intermolecular interactions and crystallographic packing arrangements. For selected complexes photomagnetic LIESST measurements have been performed revealing reversible photo-induced spin-state switching.Read less <
Origin
Hal imported