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2,2'-Dipyridylamino-based ligands with substituted alkyl chain groups and their mononuclear-Mn(II) spin crossover complexes

hal.structure.identifierSchool of Chemistry
dc.contributor.authorSCOTT, Hayley S.
hal.structure.identifierSchool of Chemistry
dc.contributor.authorMOUBARAKI, Boujemaa
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPARADIS, Nicolas
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHASTANET, Guillaume
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
hal.structure.identifierSchool of Chemistry
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorBATTEN, Stuart R.
hal.structure.identifierSchool of Chemistry
dc.contributor.authorMURRAY, Keith S.
dc.date.issued2015
dc.identifier.issn2050-7526
dc.description.abstractEnFour new alkyl chain appended dipyridylamino-substituted-s-triazine ligands have been incorporated into seven new, mononuclear MII compounds of type [MII(NCX)2(L)2] (where NCX = NCS− or NCSe− and MII = Fe or Co). These complexes have been structurally and magnetically characterised. The magnetic consequence of varying the alkyl chain length has been investigated in terms of intermolecular interactions and crystallographic packing arrangements. For selected complexes photomagnetic LIESST measurements have been performed revealing reversible photo-induced spin-state switching.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.title.en2,2'-Dipyridylamino-based ligands with substituted alkyl chain groups and their mononuclear-Mn(II) spin crossover complexes
dc.typeArticle de revue
dc.identifier.doi10.1039/c5tc00491h
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Materials Chemistry C
bordeaux.page7845-7857
bordeaux.volume3
bordeaux.issue30
bordeaux.peerReviewedoui
hal.identifierhal-01187858
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01187858v1
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