Activation of carbon dioxide by bicyclic amidines
Language
en
Article de revue
This item was published in
Journal of Organic Chemistry. 2004, vol. 69, n° 23, p. 8005-8011
American Chemical Society
English Abstract
Activation of the carbon dioxide molecule was achieved using bicyclic amidines (DBU, PMDBD, and DBN). The solution reaction of CO2 with amidines yielded the corresponding zwitterionic complexes through the formation of a ...Read more >
Activation of the carbon dioxide molecule was achieved using bicyclic amidines (DBU, PMDBD, and DBN). The solution reaction of CO2 with amidines yielded the corresponding zwitterionic complexes through the formation of a N-CO2 bond. 13C NMR data confirmed the carbamic nature of the carbamic zwitterions, DBU-CO2 and PMDBD-CO2...Read less <
English Keywords
Activation
Carbon dioxide
Bicyclic amidine
Crystallography
Origin
Hal imported