Activation of carbon dioxide by bicyclic amidines
Idioma
en
Article de revue
Este ítem está publicado en
Journal of Organic Chemistry. 2004, vol. 69, n° 23, p. 8005-8011
American Chemical Society
Resumen en inglés
Activation of the carbon dioxide molecule was achieved using bicyclic amidines (DBU, PMDBD, and DBN). The solution reaction of CO2 with amidines yielded the corresponding zwitterionic complexes through the formation of a ...Leer más >
Activation of the carbon dioxide molecule was achieved using bicyclic amidines (DBU, PMDBD, and DBN). The solution reaction of CO2 with amidines yielded the corresponding zwitterionic complexes through the formation of a N-CO2 bond. 13C NMR data confirmed the carbamic nature of the carbamic zwitterions, DBU-CO2 and PMDBD-CO2...< Leer menos
Palabras clave en inglés
Activation
Carbon dioxide
Bicyclic amidine
Crystallography
Orígen
Importado de HalCentros de investigación