Three-dimensional high spatial localization of efficient resonant energy transfer from laser-assisted precipitated silver clusters to trivalent Europium ions
PETIT, Yannick
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Centre d'Etudes Lasers Intenses et Applications [CELIA]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Centre d'Etudes Lasers Intenses et Applications [CELIA]
GALLEANI, Gustavo
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Universidade de São Paulo = University of São Paulo [USP]
See more >
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Universidade de São Paulo = University of São Paulo [USP]
PETIT, Yannick
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Centre d'Etudes Lasers Intenses et Applications [CELIA]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Centre d'Etudes Lasers Intenses et Applications [CELIA]
GALLEANI, Gustavo
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Universidade de São Paulo = University of São Paulo [USP]
< Reduce
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Universidade de São Paulo = University of São Paulo [USP]
Language
en
Article de revue
This item was published in
Crystals. 2021, vol. 11, n° 2, p. 148
MDPI
English Abstract
We report on the 3D precipitation, using a direct laser writing approach, of highly fluorescent silver clusters in a Eu 3+-doped silvercontaining zinc phosphate glass. Micro-spectroscopy of fluorescence emission shows the ...Read more >
We report on the 3D precipitation, using a direct laser writing approach, of highly fluorescent silver clusters in a Eu 3+-doped silvercontaining zinc phosphate glass. Micro-spectroscopy of fluorescence emission shows the ability to continuously adjust the local trichromatic coordinates in the CIE chromaticity diagram between red and white colors, thanks to the laser-deposited dose and resulting tunable combination of emissions from Eu 3+ and silver clusters. Moreover, CW and time-resolved FAST-FLIM spectroscopies showed a significant enhancement of the fluorescence emission of Eu 3+ ions while being co-located with UV-excited laser-inscribed silver clusters. These results demonstrate the ability to perform efficient resonant non-radiative energy transfer from excited silver clusters to Eu 3+ , allowing such energy transfer to be highly localized on demand thanks to laser inscription. Such results open the route to 3D printing of the rare earth ions emission in glass.Read less <
English Keywords
silver clusters
rare earth ions
femtosecond laser inscription
FLIM spectroscopy
resonant transfers
Dexter process
FRET process
CIE chomaticity diagram
ANR Project
Architectures photoniques intégrées inscrites par laser femtoseconde pour étalonnage en microscopie de fluorescence dans l'infrarouge - ANR-19-CE08-0021
Origin
Hal imported