Reversible switching of the electronic ground state in a pentacoordinated Cu(ii) complex.
Language
en
Article de revue
This item was published in
Chemical Communications. 2013, vol. 49, n° 71, p. 7806-7808
Royal Society of Chemistry
English Abstract
An easy reversible switching of the electronic ground state in a pentacoordinated copper(ii) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(ii) complex with a {dx(2)-y(2)}(1) ...Read more >
An easy reversible switching of the electronic ground state in a pentacoordinated copper(ii) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(ii) complex with a {dx(2)-y(2)}(1) electronic configuration leads to a flip of the ground electronic configuration from {dx(2)-y(2)}(1) to {dz(2)}(1) in the metal ion.Read less <
English Keywords
Reversible switching
Electronic ground state
Copper
Inorganic compounds
Origin
Hal imported