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Reversible switching of the electronic ground state in a pentacoordinated Cu(ii) complex.

hal.structure.identifierDepartment of Chemistry
dc.contributor.authorSASMAL, Ashok
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorSAHA, Sandeepta
hal.structure.identifierInstituto de Ciencia Molecular [ICMol]
dc.contributor.authorGOMEZ-GARCIA, Carlos J.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDESPLANCHES, Cédric
hal.structure.identifierDepartment of Chemistry [Sassari] [UNISS]
dc.contributor.authorGARRIBBA, Eugenio
hal.structure.identifierDepatment of Chemistry
dc.contributor.authorBAUZÁ, Antonio
hal.structure.identifierDepatment of Chemistry
dc.contributor.authorFRONTERA, Antonio
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorSCOTT, Reum
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorBUTCHER, Ray J.
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorMITRA, Samiran
dc.date.issued2013
dc.identifier.issn1359-7345
dc.description.abstractEnAn easy reversible switching of the electronic ground state in a pentacoordinated copper(ii) complex is reported for the first time. The simple protonation of a carboxylic group in a Cu(ii) complex with a {dx(2)-y(2)}(1) electronic configuration leads to a flip of the ground electronic configuration from {dx(2)-y(2)}(1) to {dz(2)}(1) in the metal ion.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enReversible switching
dc.subject.enElectronic ground state
dc.subject.enCopper
dc.subject.enInorganic compounds
dc.title.enReversible switching of the electronic ground state in a pentacoordinated Cu(ii) complex.
dc.typeArticle de revue
dc.identifier.doi10.1039/c3cc44276d
dc.subject.halChimie/Matériaux
bordeaux.journalChemical Communications
bordeaux.page7806-7808
bordeaux.volume49
bordeaux.issue71
bordeaux.peerReviewedoui
hal.identifierhal-00861692
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00861692v1
bordeaux.COinSctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Communications&rft.date=2013&rft.volume=49&rft.issue=71&rft.spage=7806-7808&rft.epage=7806-7808&rft.eissn=1359-7345&rft.issn=1359-7345&rft.au=SASMAL,%20Ashok&SAHA,%20Sandeepta&GOMEZ-GARCIA,%20Carlos%20J.&DESPLANCHES,%20C%C3%A9dric&GARRIBBA,%20Eugenio&rft.genre=article


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