β-Phosphorus hyperfine coupling constant in nitroxides: 5. Solvent effect
Language
en
Article de revue
This item was published in
RSC Advances. 2016-01-14, vol. 6, n° 7, p. 5653-5670
Royal Society of Chemistry
English Abstract
Recently, we published the titration of water in organic solvents and conversely using this family of nitroxides (Org. Biomol. Chem. 2015 ASAP). In this article, we show that the a b,P of persistent cyclic b-phosphorylated ...Read more >
Recently, we published the titration of water in organic solvents and conversely using this family of nitroxides (Org. Biomol. Chem. 2015 ASAP). In this article, we show that the a b,P of persistent cyclic b-phosphorylated nitroxides decreases with the normalized polarity Reichardt's constant E N T. Koppel-Palm and Kalmet-Abboud-Taft relationships were applied to get a deeper insight into the effects influencing a N and a b,P : polarity/polarizability, hydrogen bond donor property, and structuredness of the cybotactic region.Read less <
Origin
Hal imported