β-Phosphorus hyperfine coupling constant in nitroxides: 5. Solvent effect
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en
Article de revue
Ce document a été publié dans
RSC Advances. 2016-01-14, vol. 6, n° 7, p. 5653-5670
Royal Society of Chemistry
Résumé en anglais
Recently, we published the titration of water in organic solvents and conversely using this family of nitroxides (Org. Biomol. Chem. 2015 ASAP). In this article, we show that the a b,P of persistent cyclic b-phosphorylated ...Lire la suite >
Recently, we published the titration of water in organic solvents and conversely using this family of nitroxides (Org. Biomol. Chem. 2015 ASAP). In this article, we show that the a b,P of persistent cyclic b-phosphorylated nitroxides decreases with the normalized polarity Reichardt's constant E N T. Koppel-Palm and Kalmet-Abboud-Taft relationships were applied to get a deeper insight into the effects influencing a N and a b,P : polarity/polarizability, hydrogen bond donor property, and structuredness of the cybotactic region.< Réduire
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