Loading linear arrays of Cu(II) inside aromatic amide helices
Language
EN
Article de revue
This item was published in
Angewandte Chemie (International ed. in English). 2021 n° 60, p. 7p.
English Abstract
The very stable helices of 8-amino-2-quinolinecar-boxylic acid oligoamides are shown to uptake CuIIions in theircavity through deprotonation of their amide functions with minimal alteration of their shape, unlike most ...Read more >
The very stable helices of 8-amino-2-quinolinecar-boxylic acid oligoamides are shown to uptake CuIIions in theircavity through deprotonation of their amide functions with minimal alteration of their shape, unlike most metallo-organicstructures which generally differ from their organic precursors.The outcome is the formation of intramolecular linear arrays of a defined number of CuIIcenters (up to sixteen in this study)at a 3 distance, forming a molecular mimic of a metal wirecompletely surrounded by an organic sheath. The helices packin the solid state so that the arrays of CuIIextend intermolecularly. Conductive-AFM and cyclic voltammetry suggest thatelectrons are transported throughout the metal-loaded helices in contrast with hole transport observed for analogous foldamers devoid of metal ions.Read less <
English Keywords
Cu(II)coordination
electron transport
helix
metallofoldamers
self-assembled monolayers
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Les voies de signalisation du récepteur 5-HT6: de nouvelles cibles pour le traitement de la douleur neuropathique? - ANR-19-CE18-0018