MAILHE, Clément; ACHCHAQ, Fouzia; DUQUESNE, Marie

doi:10.1016/j.tca.2020.178580

Métadonnées

Afficher la notice complète

Licence d’utilisation du document

MAILHE, Clément
Institut de Mécanique et d'Ingénierie [I2M]

ACHCHAQ, Fouzia

Institut de Mécanique et d'Ingénierie [I2M]

DUQUESNE, Marie

Institut de Mécanique et d'Ingénierie [I2M]

Langue

Article de revue

Ce document a été publié dans

Thermochimica Acta. 2020-05, vol. 687, p. 1-9

Elsevier

Résumé en anglais

The solid-liquid equilibria (SLE) modeling of fatty acids binary systems is known as a challenging topic. Due to their complex phase diagrams and to their inherent nature to polymorphism, the modeling of the solid-liquid equilibria of the fatty acids blends requires a significant amount of data obtained with numerous techniques. The infrared thermography method (IRT) proves to be an interesting alternative by providing large quantities of phase transitions data, including the potential detection of the polymorphic ones. In this work, the applicability of this method for SLE modeling is assessed based on two criteria: i) the accuracy of empirical and theoretical models is assessed in comparison with IRT data; ii) the polymorphic transition temperatures detected via IRT are used as inputs in a model using polymorphic transition enthalpies as adjusting parameters. Polymorphic transitions data is compared to literature and to DSC measurements to evaluate the reliability of IRT for polymorphic transitions detection and of the estimated enthalpies consistency.< Réduire

Mots clés en anglais

Solid-liquid equilibrium

Phase diagram

Polymorphism

Infrared thermography

Organic materials

Métadonnées

Partager cette publication !

Licence d’utilisation du document

Applications of an infrared thermography method for solid-liquid equilibria modeling of organic binary systems

Langue

Ce document a été publié dans

Résumé en anglais

Mots clés en anglais

URI

DOI

Origine

Unités de recherche