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dc.rights.licenseopenen_US
hal.structure.identifierUnité de Recherche Oenologie [Villenave d'Ornon] [OENO]
dc.contributor.authorFLOCH, Morgan
dc.contributor.authorSHINKARUK, Svitlana
hal.structure.identifierUnité de Recherche Oenologie [Villenave d'Ornon] [OENO]
dc.contributor.authorDARRIET, Philippe
IDREF: 077788834
hal.structure.identifierUnité de Recherche Oenologie [Villenave d'Ornon] [OENO]
dc.contributor.authorPONS, Alexandre
dc.date.accessioned2021-01-25T14:27:26Z
dc.date.available2021-01-25T14:27:26Z
dc.date.issued2016-01-23
dc.identifier.issn0021-8561en_US
dc.identifier.urioai:crossref.org:10.1021/acs.jafc.5b05733
dc.identifier.urihttps://oskar-bordeaux.fr/handle/20.500.12278/25988
dc.description.abstractEnVanillylthiol, a chemical compound reminiscent of clove and smoke, has been identified for the first time in young red and dry white wines. The chemical structure of this new aroma was confirmed by original chemical synthesis. Vanillylthiol was prepared by a two-step procedure from vanillin. The conversion of vanillin to divanillyl disulfide was easily achieved by treatment with an inorganic sulfur-donor reagent. Reduction of the disulfide gave the target thiol in good yield. The quantification of vanillylthiol in wine was performed by nonspecific liquid/liquid extraction (CH2Cl2), separation of the volatile compounds using gas chromatography, and specific detection using tandem mass spectrometry (triple quadrupole). Vanillylthiol was found particularly in young wines aged in new oak barrels. These wines contained between a few 50 ng/L to more than 8300 ng/L. The highest levels were found in red wines aged 12 months in new oak barrels. Given its perception threshold in a wine model solution (3.8 μg/L), vanillylthiol may contribute to the spicy, clove-like flavor of red wines aged in oak barrels.
dc.language.isoENen_US
dc.sourcecrossref
dc.subject.enwine
dc.subject.enaroma
dc.subject.enthiol
dc.subject.enoak barrel
dc.subject.enaging
dc.title.enIdentification and Organoleptic Contribution of Vanillylthiol in Wines
dc.title.alternativeJ. Agric. Food Chem.en_US
dc.typeArticle de revueen_US
dc.identifier.doi10.1021/acs.jafc.5b05733en_US
dc.subject.halSciences du Vivant [q-bio]/Biologie végétaleen_US
dc.identifier.pubmed26806420en_US
bordeaux.journalJournal of Agricultural and Food Chemistryen_US
bordeaux.page1318-1325en_US
bordeaux.volume64en_US
bordeaux.hal.laboratoriesOenologie - EA 4577en_US
bordeaux.issue6en_US
bordeaux.institutionBordeaux INPen_US
bordeaux.institutionUniversité de Bordeauxen_US
bordeaux.peerReviewedouien_US
bordeaux.inpressnonen_US
bordeaux.import.sourcedissemin
hal.exportfalse
workflow.import.sourcedissemin
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