MATMOUR, Rachid; JONCHERAY, Thomas J.; GNANOU, Yves; DURAN, Randolph S.

doi:10.1016/j.jcis.2007.02.065

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MATMOUR, Rachid
Laboratoire de Chimie des polymères organiques [LCPO]

JONCHERAY, Thomas J.
Department of Chemistry and Center for Macromolecular Science and Engineering

GNANOU, Yves
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering

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Journal of Colloid and Interface Science. 2007, vol. 311, n° 1, p. 315-321

Elsevier

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A novel approach to two-dimensionally crosslink polydienes at the air/water interface is proposed. The acid-catalyzed condensation of the triethoxysilane pendant groups of triethoxysilane-functionalized polybutadiene chains at the air/water interface successfully led to the formation of an insoluble crosslinked material which could be directly removed from the water surface. The efficiency of the cross-linking reaction was demonstrated through surface pressure measurements such as surface pressure-mean molecular area isotherms recorded at different reaction times and isobar experiments for different subphase pH values. The evolution of the monolayer topography during cross-linking was studied by atomic force microscopy imaging of the Langmuir-Blodgett films. (C) 2007 Elsevier Inc. All rights reserved< Réduire

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triethoxysilane

air/water interface

Langmuir-Blodgett films

polybutadiene

two-dimensional cross-linking

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Cross-linking of polybutadiene at the air/water interface: Toward an easy access to two-dimensional polymeric materials

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