Cross-linking of polybutadiene at the air/water interface: Toward an easy access to two-dimensional polymeric materials
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | MATMOUR, Rachid | |
| hal.structure.identifier | Department of Chemistry and Center for Macromolecular Science and Engineering | |
| dc.contributor.author | JONCHERAY, Thomas J. | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| hal.structure.identifier | Team 1 LCPO : Polymerization Catalyses & Engineering | |
| dc.contributor.author | GNANOU, Yves | |
| hal.structure.identifier | Department of Chemistry and Center for Macromolecular Science and Engineering | |
| dc.contributor.author | DURAN, Randolph S. | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2007 | |
| dc.identifier.issn | 0021-9797 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20829 | |
| dc.description.abstractEn | A novel approach to two-dimensionally crosslink polydienes at the air/water interface is proposed. The acid-catalyzed condensation of the triethoxysilane pendant groups of triethoxysilane-functionalized polybutadiene chains at the air/water interface successfully led to the formation of an insoluble crosslinked material which could be directly removed from the water surface. The efficiency of the cross-linking reaction was demonstrated through surface pressure measurements such as surface pressure-mean molecular area isotherms recorded at different reaction times and isobar experiments for different subphase pH values. The evolution of the monolayer topography during cross-linking was studied by atomic force microscopy imaging of the Langmuir-Blodgett films. (C) 2007 Elsevier Inc. All rights reserved | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | triethoxysilane | |
| dc.subject.en | air/water interface | |
| dc.subject.en | Langmuir-Blodgett films | |
| dc.subject.en | polybutadiene | |
| dc.subject.en | two-dimensional cross-linking | |
| dc.title.en | Cross-linking of polybutadiene at the air/water interface: Toward an easy access to two-dimensional polymeric materials | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.jcis.2007.02.065 | |
| dc.subject.hal | Chimie/Polymères | |
| bordeaux.journal | Journal of Colloid and Interface Science | |
| bordeaux.page | 315-321 | |
| bordeaux.volume | 311 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 1 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00275932 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00275932v1 | |
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