Synthesis and characterization of diaminodithio- and aminotrithiophosphoric acid esters
TATON, Daniel
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
< Réduire
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Langue
en
Article de revue
Ce document a été publié dans
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. 2007, vol. 182, n° 6, p. 1233-1244
Résumé en anglais
The synthesis and characterization of a series of five new diaminodithiophosphoric acid esters ((RRN)-R-1-N-2)(2)P(S) SR and five new aminotrithiophosphoric acid esters ((RRN)-R-1-N-2)P(S)(SR)(2) are described. The structure ...Lire la suite >
The synthesis and characterization of a series of five new diaminodithiophosphoric acid esters ((RRN)-R-1-N-2)(2)P(S) SR and five new aminotrithiophosphoric acid esters ((RRN)-R-1-N-2)P(S)(SR)(2) are described. The structure of two of these compounds, the diaminodithio derivative (iPr(2)N)(2)P(S)SCH2Ph and the aminotrithio derivative (iPr(2)N)P(S)(SCH2Ph)(2) , has been determined by single crystal X-ray diffraction. These series of compounds are potentially usable as agents for reversible addition-fragmentation chain transfer polymerization.< Réduire
Mots clés en anglais
thiols
reversible addition-fragmentation chain transfer (RAFT) agents
aminotrithiophosphoric acid esters
amines
diaminodithiophosphoric acid esters
Origine
Importé de halUnités de recherche