Synthesis and characterization of diaminodithio- and aminotrithiophosphoric acid esters
TATON, Daniel
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
< Leer menos
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Idioma
en
Article de revue
Este ítem está publicado en
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS. 2007, vol. 182, n° 6, p. 1233-1244
Resumen en inglés
The synthesis and characterization of a series of five new diaminodithiophosphoric acid esters ((RRN)-R-1-N-2)(2)P(S) SR and five new aminotrithiophosphoric acid esters ((RRN)-R-1-N-2)P(S)(SR)(2) are described. The structure ...Leer más >
The synthesis and characterization of a series of five new diaminodithiophosphoric acid esters ((RRN)-R-1-N-2)(2)P(S) SR and five new aminotrithiophosphoric acid esters ((RRN)-R-1-N-2)P(S)(SR)(2) are described. The structure of two of these compounds, the diaminodithio derivative (iPr(2)N)(2)P(S)SCH2Ph and the aminotrithio derivative (iPr(2)N)P(S)(SCH2Ph)(2) , has been determined by single crystal X-ray diffraction. These series of compounds are potentially usable as agents for reversible addition-fragmentation chain transfer polymerization.< Leer menos
Palabras clave en inglés
thiols
reversible addition-fragmentation chain transfer (RAFT) agents
aminotrithiophosphoric acid esters
amines
diaminodithiophosphoric acid esters
Orígen
Importado de HalCentros de investigación