Synthesis and Self-Assembly Properties of Peptide-Polylactide Block Copolymers
CAILLOL, Sylvain
Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
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Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
CAILLOL, Sylvain
Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
< Réduire
Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
Langue
en
Article de revue
Ce document a été publié dans
Macromolecules. 2003, vol. 36, n° 4, p. 1118-1124
American Chemical Society
Résumé en anglais
Poly(L-lactide-b-gamma-benzyl glutamate) copolymers with various block lengths were synthesized by sequential ring-opening polymerization of L-lactide and N-carboxyanhydride of gamma-benzyl glutamate. The copolymers were ...Lire la suite >
Poly(L-lactide-b-gamma-benzyl glutamate) copolymers with various block lengths were synthesized by sequential ring-opening polymerization of L-lactide and N-carboxyanhydride of gamma-benzyl glutamate. The copolymers were characterized by SEC and NMR spectrometry. DSC and SAXS data suggested that the copolymers were phase-separated in domains containing either crystalline PLLA or liquid-crystalline columnar hexagonal morphology of PBLG. When varying the temperature, reversible local order-order transition could be observed on these diblock copolymers.< Réduire
Mots clés en anglais
SUPRAMOLECULAR MATERIALS
N-CARBOXYANHYDRIDES
POLYMERS
Origine
Importé de halUnités de recherche