Synthesis and Self-Assembly Properties of Peptide-Polylactide Block Copolymers
CAILLOL, Sylvain
Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
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Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
CAILLOL, Sylvain
Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
< Leer menos
Institut Charles Gerhardt Montpellier - Institut de Chimie Moléculaire et des Matériaux de Montpellier [ICGM ICMMM]
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en
Article de revue
Este ítem está publicado en
Macromolecules. 2003, vol. 36, n° 4, p. 1118-1124
American Chemical Society
Resumen en inglés
Poly(L-lactide-b-gamma-benzyl glutamate) copolymers with various block lengths were synthesized by sequential ring-opening polymerization of L-lactide and N-carboxyanhydride of gamma-benzyl glutamate. The copolymers were ...Leer más >
Poly(L-lactide-b-gamma-benzyl glutamate) copolymers with various block lengths were synthesized by sequential ring-opening polymerization of L-lactide and N-carboxyanhydride of gamma-benzyl glutamate. The copolymers were characterized by SEC and NMR spectrometry. DSC and SAXS data suggested that the copolymers were phase-separated in domains containing either crystalline PLLA or liquid-crystalline columnar hexagonal morphology of PBLG. When varying the temperature, reversible local order-order transition could be observed on these diblock copolymers.< Leer menos
Palabras clave en inglés
SUPRAMOLECULAR MATERIALS
N-CARBOXYANHYDRIDES
POLYMERS
Orígen
Importado de HalCentros de investigación