Micellar aggregation in blends of linear and cyclic poly(styrene-b-isoprene) diblock copolymers
DEFFIEUX, Alain
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Laboratoire de Chimie des polymères organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
PUTAUX, Jean-Luc
Laboratoire de Chimie des polymères organiques [LCPO]
Centre de Recherches sur les Macromolécules Végétales [CERMAV]
Laboratoire de Chimie des polymères organiques [LCPO]
Centre de Recherches sur les Macromolécules Végétales [CERMAV]
BORSALI, Redouane
Laboratoire de Chimie des polymères organiques [LCPO]
Team 3 LCPO : Polymer Self-Assembly & Life Sciences
< Reduce
Laboratoire de Chimie des polymères organiques [LCPO]
Team 3 LCPO : Polymer Self-Assembly & Life Sciences
Language
en
Article de revue
This item was published in
Langmuir. 2005, vol. 21, n° 20, p. 9085-9090
American Chemical Society
English Abstract
The morphology of micelles formed from blends of linear and cyclic poly(styrene-b-isoprene) (PS-b-PI) block copolymers has been investigated in solution using dynamic light scattering (DLS) and in thin solid deposits by ...Read more >
The morphology of micelles formed from blends of linear and cyclic poly(styrene-b-isoprene) (PS-b-PI) block copolymers has been investigated in solution using dynamic light scattering (DLS) and in thin solid deposits by atomic force microscopy (AFM) and transmission electron microscopy under cryogenic conditions (cryo-TEM). Micelles of the pure cyclic PS290-b-PI110 copolymers are wormlike cylindrical objects built by unidirectional aggregation of 33 nm wide sunflower micelles, while the linear block copolymer having the same volume fraction and molar mass forms spherical micelles 40 nm in diameter. The DLS, AFM, and cryo-TEM results consistently show that the addition of the linear copolymer (even for amounts as low as 5% w/w) to the cyclic copolymer rather favors the formation of spherical micelles at the expense of the cylindrical aggregates. Those results clearly show that the linear block copolymer chains can be used to stabilize the thermodynamically unstable elementary sunflower micelle. The thermal stability of the micelles (from the pure copolymers and from the blends) has been examined in solid deposits with in situ AFM measurements. Coalescence starts at about 70 degrees C, and the surface roughness shows a two-step decrease toward a fully homogeneous and flat structure.Read less <
English Keywords
WORMLIKE MICELLES
FORMING COPOLYMERS
HOMOPOLYMER BLENDS
SELECTIVE SOLVENTS
EXCLUDED-VOLUME INTERACTIONS
SMALL-ANGLE NEUTRON
BLOCK-COPOLYMER
ORDERED STRUCTURE
PHASE-EQUILIBRIA
LIGHT-SCATTERING
Origin
Hal imported