Unexpected matrix interactions in liquid secondary ion mass spectrometry of two pyranosyl mercaptans.
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en
Article de revue
Ce document a été publié dans
Rapid Communications in Mass Spectrometry. 2011, vol. 25, n° 10, p. 1399-406
Wiley
Résumé en anglais
An unexpected interaction with a thioglycerol matrix appeared in the liquid secondary ion mass spectrometry (LSIMS) spectra of two pyranosyl mercaptans [2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranose (1a) and 2,3,4,6-te ...Lire la suite >
An unexpected interaction with a thioglycerol matrix appeared in the liquid secondary ion mass spectrometry (LSIMS) spectra of two pyranosyl mercaptans [2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranose (1a) and 2,3,4,6-tetra-O-acetyl-1,5-dithio-β-D-glucopyranose (1b)] often used to prepare glucosinolates, important thiosaccharidic metabolites found in all plants of the order Brassicales. The reactions, probably occurring in the solvent cage, seem to involve radical mechanisms.< Réduire
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