Unexpected matrix interactions in liquid secondary ion mass spectrometry of two pyranosyl mercaptans.
| dc.rights.license | open | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | GARDRAT, Christian | |
| hal.structure.identifier | Institut de Chimie Organique et Analytique [ICOA] | |
| dc.contributor.author | JOSEPH, Benoît | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | VITRY, Christiane | |
| hal.structure.identifier | Laboratoire de Chimie des polymères organiques [LCPO] | |
| dc.contributor.author | CASTELLAN, Alain | |
| hal.structure.identifier | Institut de Chimie Organique et Analytique [ICOA] | |
| dc.contributor.author | ROLLIN, Patrick | |
| dc.date.accessioned | 2020 | |
| dc.date.available | 2020 | |
| dc.date.issued | 2011 | |
| dc.identifier.issn | 0951-4198 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/20500 | |
| dc.description.abstractEn | An unexpected interaction with a thioglycerol matrix appeared in the liquid secondary ion mass spectrometry (LSIMS) spectra of two pyranosyl mercaptans [2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranose (1a) and 2,3,4,6-tetra-O-acetyl-1,5-dithio-β-D-glucopyranose (1b)] often used to prepare glucosinolates, important thiosaccharidic metabolites found in all plants of the order Brassicales. The reactions, probably occurring in the solvent cage, seem to involve radical mechanisms. | |
| dc.language.iso | en | |
| dc.publisher | Wiley | |
| dc.title.en | Unexpected matrix interactions in liquid secondary ion mass spectrometry of two pyranosyl mercaptans. | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/rcm.4998 | |
| dc.subject.hal | Chimie/Chimie organique | |
| bordeaux.journal | Rapid Communications in Mass Spectrometry | |
| bordeaux.page | 1399-406 | |
| bordeaux.volume | 25 | |
| bordeaux.hal.laboratories | Laboratoire de Chimie des Polymères Organiques (LCPO) - UMR 5629 | * |
| bordeaux.issue | 10 | |
| bordeaux.institution | Bordeaux INP | |
| bordeaux.institution | Université de Bordeaux | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00691437 | |
| hal.version | 1 | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00691437v1 | |
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