TUNC, Deniz; CARLOTTI, Stéphane; HASSEN, Bouchekif; AMEDURI, Bruno; JÉRÔME, Christine; DESBOIS, Philippe; PHILIPPE, Lecomte

doi:10.1016/j.eurpolymj.2015.08.030

Métadonnées

Licence d’utilisation du document

TUNC, Deniz
Laboratoire de Chimie des Polymères Organiques [LCPO]

CARLOTTI, Stéphane
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering

HASSEN, Bouchekif
Laboratoire de Chimie des Polymères Organiques [LCPO]

Langue

Article de revue

Ce document a été publié dans

European Polymer Journal. 2015, vol. 71, p. 575–584

Elsevier

Résumé en anglais

Aliphatic polyamide (PA) bearing fluorinated groups was synthesized in bulk withperfluorobutyryl-substituted a-amino-e-caprolactam and e-caprolactam by anionic ringopeningpolymerization (AROP). The fluorinated monomer was obtained by condensationbetween cyclic lysine (i.e. a-amino-e-caprolactam) and perfluorobutyryl chloride. Theeffect of the fluorinated monomer fraction onto the AROP of e-caprolactam was monitoredby the exothermicity of this polymerization versus time. The properties and characteristicsof the resulting polymers were studied by with differential scanning calorimetry,thermogravimetry, magic angle spinning NMR, FT-IR, and contact angle measurements.Polyamides bearing fluorinated groups exhibited better thermal stability than polyamide6 (PA6) as well as a higher hydrophobic surface character as evidenced by surface tensionmeasurements. The glass transition temperature of polyamide 6 was 53 C and rose to58 C for a PA bearing fluorinated moieties, while fluorinated monomer insertion induceda decrease of the melting points from 216 to 198 C. These copolymers displayed amaximum degradation temperature of 390 C as compared to the 310 C for PA6, and theirsurface energies decreased from 49.4 mN cm1 (PA6 value) to 44.1 mN cm1< Réduire

Mots clés en anglais

Surface energies

Magic angle spinning NMR

Perfluorobutyryl group

alpha-Amino-e-caprolactam

Aliphatic polyamide

Anionic ring-opening polymerization

Hydrophobic surface

Métadonnées

Partager cette publication !

Licence d’utilisation du document

Synthesis of aliphatic polyamide bearing fluorinated groupsfrom e-caprolactam and modified cyclic lysine

Langue

Ce document a été publié dans

Résumé en anglais

Mots clés en anglais

URI

DOI

Origine

Unités de recherche