Dimerization of abietic acid for the design of renewable polymers by ADMET
GRAU, Etienne
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
CARLOTTI, Stéphane
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
See more >
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
GRAU, Etienne
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
CARLOTTI, Stéphane
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 1 LCPO : Polymerization Catalyses & Engineering
GRELIER, Stéphane
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
CRAMAIL, Henri
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
< Reduce
Laboratoire de Chimie des Polymères Organiques [LCPO]
Team 2 LCPO : Biopolymers & Bio-sourced Polymers
Language
en
Article de revue
This item was published in
European Polymer Journal. 2015
Elsevier
English Abstract
Cationic dimerization of abietic acid, a resource from tall oil or pines, was investigated. Diacid dimers were obtained in good yields and isolated from abietic acid. These diacids were esterified with undecenol to give ...Read more >
Cationic dimerization of abietic acid, a resource from tall oil or pines, was investigated. Diacid dimers were obtained in good yields and isolated from abietic acid. These diacids were esterified with undecenol to give bisunsaturated derivatives. The latter were then homopolymerized or copolymerized with undecenyl undecenoate employing ADMET methodology, leading to thermoplastic polymers with molar mass up to 40,000 g/mol. While the copolymers exhibit melting points around 50 degrees C, the homopolymer of abietic acid dimer is amorphous with a Tg around 100 degrees C.Read less <
English Keywords
DIMER
ADDUCT
RESOURCE
DERIVATIVES
ROSIN
CHROMATOGRAPHY
Abietic acid dimers
ADMET
ACRYLIC-ACID
CONTROLLED POLYMERIZATION
LEVOPIMARIC ACID
vegetable oil
thermoplastic polymers
Origin
Hal imported