Relationship between the two-component system 1-Br-adamantane + 1-Cl-adamantane and the high-pressure properties of the pure components
Idioma
en
Article de revue
Este ítem está publicado en
Fluid Phase Equilibria. 2018, vol. 459, p. 219-229
Elsevier
Resumen en inglés
The temperature composition phase diagram of the two component system 1 Br adamantane and 1 Cl adamantane has been determined by means of thermal analysis techniques and X ray powder diffraction from the low temperature ...Leer más >
The temperature composition phase diagram of the two component system 1 Br adamantane and 1 Cl adamantane has been determined by means of thermal analysis techniques and X ray powder diffraction from the low temperature phase to the liquid state. The crossed isopolymorphism formalism has been applied to the two component system to infer the normal pressure properties of the orthorhombic metastable phase of 1 Cl adamantane at normal pressure. The experimental pressure temperature phase diagrams for the involved compounds are related to the two phase equilibria determined at normal pressure and inferences about the monotropic behavior of the aforementioned orthorhombic phase are discussed.< Leer menos
Palabras clave en inglés
High pressure
Polymorphism
Two-component system
Orígen
Importado de HalCentros de investigación