Relationship between the two-component system 1-Br-adamantane + 1-Cl-adamantane and the high-pressure properties of the pure components
Language
en
Article de revue
This item was published in
Fluid Phase Equilibria. 2018, vol. 459, p. 219-229
Elsevier
English Abstract
The temperature composition phase diagram of the two component system 1 Br adamantane and 1 Cl adamantane has been determined by means of thermal analysis techniques and X ray powder diffraction from the low temperature ...Read more >
The temperature composition phase diagram of the two component system 1 Br adamantane and 1 Cl adamantane has been determined by means of thermal analysis techniques and X ray powder diffraction from the low temperature phase to the liquid state. The crossed isopolymorphism formalism has been applied to the two component system to infer the normal pressure properties of the orthorhombic metastable phase of 1 Cl adamantane at normal pressure. The experimental pressure temperature phase diagrams for the involved compounds are related to the two phase equilibria determined at normal pressure and inferences about the monotropic behavior of the aforementioned orthorhombic phase are discussed.Read less <
English Keywords
High pressure
Polymorphism
Two-component system
Origin
Hal imported