Metal-to-Metal Electron Transfer in Co/Fe Prussian Blue Molecular Analogues: The Ultimate Miniaturization.
KOUMOUSI, Evangelia S.
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
JEON, Ie-Rang
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
See more >
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
KOUMOUSI, Evangelia S.
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
JEON, Ie-Rang
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
< Reduce
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Language
en
Article de revue
This item was published in
Journal of the American Chemical Society. 2014, vol. 136, n° 44, p. 15461-15464
American Chemical Society
English Abstract
Co/Fe Prussian Blue analogues are known to display both thermally and light induced electron transfer attributed to the switching between diamagnetic {Fe(II)LS(μ-CN)Co(III)LS} and paramagnetic {Fe(III)LS(μ-CN)Co(II)HS} ...Read more >
Co/Fe Prussian Blue analogues are known to display both thermally and light induced electron transfer attributed to the switching between diamagnetic {Fe(II)LS(μ-CN)Co(III)LS} and paramagnetic {Fe(III)LS(μ-CN)Co(II)HS} pairs (LS = low spin; HS = high spin). In this work, a dinuclear cyanido-bridged Co/Fe complex, the smallest {Fe(μ-CN)Co} moiety at the origin of the remarkable physical properties of these systems, has been designed by a rational building-block approach. Combined structural, spectroscopic, magnetic and photomagnetic studies reveal that a metal-to-metal electron transfer that can be triggered in solid state by light, temperature and solvent contents, is observed for the first time in a dinuclear complex.Read less <
ANR Project
Synthèse et étude de chaines aimant photocommutables - ANR-12-PDOC-0038
Origin
Hal imported