A new family of [CuIILnIIIMV] heterotrimetallic complexes (Ln = La, Gd, Tb; M = Mo, W): model systems to probe exchange interactions and single-molecule magnet properties
ALEXANDRU, Maria-Gabriela
Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
Department of Inorganic Chemistry Physical Chemistry and Electrochemistry
Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
Department of Inorganic Chemistry Physical Chemistry and Electrochemistry
MADALAN, Augustin M.
Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
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Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
ALEXANDRU, Maria-Gabriela
Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
Department of Inorganic Chemistry Physical Chemistry and Electrochemistry
Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
Department of Inorganic Chemistry Physical Chemistry and Electrochemistry
MADALAN, Augustin M.
Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
JEON, Ie-Rang
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Centre de recherches Paul Pascal [CRPP]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
MATHONIÈRE, Corine
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Université de Bordeaux [UB]
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Université de Bordeaux [UB]
ANDRUH, Marius
Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
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Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
Idioma
en
Article de revue
Este ítem está publicado en
Dalton Transactions. 2016-03-09, vol. 45, p. pp. 7642-7649
Royal Society of Chemistry
Resumen en inglés
Four isostructural trinuclear 3d–4f–4(5)d heterotrimetallic complexes, with the general formula [L2CuLn(H2O)5(μ-NC)M(CN)7], were obtained from the association of binuclear 3d–4f complexes and {MV(CN)8}3− metalloligands (M ...Leer más >
Four isostructural trinuclear 3d–4f–4(5)d heterotrimetallic complexes, with the general formula [L2CuLn(H2O)5(μ-NC)M(CN)7], were obtained from the association of binuclear 3d–4f complexes and {MV(CN)8}3− metalloligands (M = Mo, Ln = La 1; M = W, Ln = La 2; M = Mo, Ln = Gd 3; M = Mo; Ln = Tb 4, where H2L2 = 1,2-ethanediylbis(2-iminomethylene-6-methoxy-phenol)). The metalloligand coordinates through a single-cyanido group at the apical position of the copper(II) ion belonging to the {CuIILnIII} binuclear complex.....< Leer menos
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