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hal.structure.identifierCoordination and Supramolecular Chemistry Laboratory
dc.contributor.authorVISINESCU, Diana
hal.structure.identifierFaculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
hal.structure.identifierDepartment of Inorganic Chemistry Physical Chemistry and Electrochemistry
dc.contributor.authorALEXANDRU, Maria-Gabriela
hal.structure.identifierFaculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
dc.contributor.authorMADALAN, Augustin M.
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorJEON, Ie-Rang
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierUniversité de Bordeaux [UB]
dc.contributor.authorMATHONIÈRE, Corine
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
hal.structure.identifierUniversité de Bordeaux [UB]
dc.contributor.authorCLÉRAC, Rodolphe
hal.structure.identifierFaculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest
dc.contributor.authorANDRUH, Marius
dc.date.issued2016-03-09
dc.identifier.issn1477-9226
dc.description.abstractEnFour isostructural trinuclear 3d–4f–4(5)d heterotrimetallic complexes, with the general formula [L2CuLn(H2O)5(μ-NC)M(CN)7], were obtained from the association of binuclear 3d–4f complexes and {MV(CN)8}3− metalloligands (M = Mo, Ln = La 1; M = W, Ln = La 2; M = Mo, Ln = Gd 3; M = Mo; Ln = Tb 4, where H2L2 = 1,2-ethanediylbis(2-iminomethylene-6-methoxy-phenol)). The metalloligand coordinates through a single-cyanido group at the apical position of the copper(II) ion belonging to the {CuIILnIII} binuclear complex.....
dc.description.sponsorshipIngénierie Cristalline de Matériaux Moléculaires Multifonctionnels - ANR-12-IS07-0004
dc.description.sponsorshipConception de décodeurs FEC basés sur l'arithmétique imprécise et leur optimisation en termes de consommation énergétique, surface et débit - ANR-13-IS03-0003
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.title.enA new family of [CuIILnIIIMV] heterotrimetallic complexes (Ln = La, Gd, Tb; M = Mo, W): model systems to probe exchange interactions and single-molecule magnet properties
dc.typeArticle de revue
dc.identifier.doi10.1039/c6dt00614k
dc.subject.halChimie/Matériaux
bordeaux.journalDalton Transactions
bordeaux.pagepp. 7642-7649
bordeaux.volume45
bordeaux.peerReviewedoui
hal.identifierhal-01313062
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-01313062v1
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