A new family of [CuIILnIIIMV] heterotrimetallic complexes (Ln = La, Gd, Tb; M = Mo, W): model systems to probe exchange interactions and single-molecule magnet properties
hal.structure.identifier | Coordination and Supramolecular Chemistry Laboratory | |
dc.contributor.author | VISINESCU, Diana | |
hal.structure.identifier | Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest | |
hal.structure.identifier | Department of Inorganic Chemistry Physical Chemistry and Electrochemistry | |
dc.contributor.author | ALEXANDRU, Maria-Gabriela | |
hal.structure.identifier | Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest | |
dc.contributor.author | MADALAN, Augustin M. | |
hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | JEON, Ie-Rang | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
hal.structure.identifier | Université de Bordeaux [UB] | |
dc.contributor.author | MATHONIÈRE, Corine | |
hal.structure.identifier | Centre de recherches Paul Pascal [CRPP] | |
hal.structure.identifier | Université de Bordeaux [UB] | |
dc.contributor.author | CLÉRAC, Rodolphe | |
hal.structure.identifier | Faculty of Applied Chemistry and Materials Science, University Politehnica of Bucharest | |
dc.contributor.author | ANDRUH, Marius | |
dc.date.issued | 2016-03-09 | |
dc.identifier.issn | 1477-9226 | |
dc.description.abstractEn | Four isostructural trinuclear 3d–4f–4(5)d heterotrimetallic complexes, with the general formula [L2CuLn(H2O)5(μ-NC)M(CN)7], were obtained from the association of binuclear 3d–4f complexes and {MV(CN)8}3− metalloligands (M = Mo, Ln = La 1; M = W, Ln = La 2; M = Mo, Ln = Gd 3; M = Mo; Ln = Tb 4, where H2L2 = 1,2-ethanediylbis(2-iminomethylene-6-methoxy-phenol)). The metalloligand coordinates through a single-cyanido group at the apical position of the copper(II) ion belonging to the {CuIILnIII} binuclear complex..... | |
dc.description.sponsorship | Ingénierie Cristalline de Matériaux Moléculaires Multifonctionnels - ANR-12-IS07-0004 | |
dc.description.sponsorship | Conception de décodeurs FEC basés sur l'arithmétique imprécise et leur optimisation en termes de consommation énergétique, surface et débit - ANR-13-IS03-0003 | |
dc.language.iso | en | |
dc.publisher | Royal Society of Chemistry | |
dc.title.en | A new family of [CuIILnIIIMV] heterotrimetallic complexes (Ln = La, Gd, Tb; M = Mo, W): model systems to probe exchange interactions and single-molecule magnet properties | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1039/c6dt00614k | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Dalton Transactions | |
bordeaux.page | pp. 7642-7649 | |
bordeaux.volume | 45 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-01313062 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-01313062v1 | |
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