Revisited crystal symmetry of the high-spin form of the iron (II) spin-crossover complex dicyano[2,13-dimethyl-6,9-dioxa-3,12,18-triazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene]iron(II) monohydrate
Language
en
Article de revue
This item was published in
Acta Crystallographica Section C : Crystal Structure Communications [1968-2013]. 2004, vol. 60, p. m587-m589
International Union of Crystallography
English Abstract
The title iron(II) complex, [Fe(CN)2(C15H23N3O2)]·H2O, is of interest to the spin-crossover community because of its unusual temperature-dependent magnetic behaviour as well as its relatively high relaxation temperature ...Read more >
The title iron(II) complex, [Fe(CN)2(C15H23N3O2)]·H2O, is of interest to the spin-crossover community because of its unusual temperature-dependent magnetic behaviour as well as its relatively high relaxation temperature for the light-induced spin-crossover phenomenon. Structural modifications are strongly suspected to cause the unusual thermal spin-crossover features. Recently, the high-spin crystal structure has been reported but with an inadequate space group...Read less <
English Keywords
[Fe(CN)2(C15H23N3O2)]·H2O
Crystal structure
Iron(II)
Spin crossover
Origin
Hal imported