Activation of carbon dioxide by bicyclic amidines
Langue
en
Article de revue
Ce document a été publié dans
Journal of Organic Chemistry. 2004, vol. 69, n° 23, p. 8005-8011
American Chemical Society
Résumé en anglais
Activation of the carbon dioxide molecule was achieved using bicyclic amidines (DBU, PMDBD, and DBN). The solution reaction of CO2 with amidines yielded the corresponding zwitterionic complexes through the formation of a ...Lire la suite >
Activation of the carbon dioxide molecule was achieved using bicyclic amidines (DBU, PMDBD, and DBN). The solution reaction of CO2 with amidines yielded the corresponding zwitterionic complexes through the formation of a N-CO2 bond. 13C NMR data confirmed the carbamic nature of the carbamic zwitterions, DBU-CO2 and PMDBD-CO2...< Réduire
Mots clés en anglais
Activation
Carbon dioxide
Bicyclic amidine
Crystallography
Origine
Importé de halUnités de recherche