VELÁZQUEZ, Matias; BERT, Fabrice; MENDELS, Philippe; DENUX, Dominique; VEBER, Philippe; LAHAYE, Michel; LABRUGÈRE, Christine

doi:10.1016/j.jcrysgro.2019.125372

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VELÁZQUEZ, Matias
Science et Ingénierie des Matériaux et Procédés [SIMaP]

BERT, Fabrice
Laboratoire de Physique des Solides [LPS]

MENDELS, Philippe
Laboratoire de Physique des Solides [LPS]

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Article de revue

Ce document a été publié dans

Journal of Crystal Growth. 2020, vol. 531, p. 125372 (4 p.)

Elsevier

Résumé en anglais

The aqueous solution growth of mm-sized, pure, 17O- or D-enriched herbertsmithite ZnxCu4-x(OH)6Cl2 single crystals is presented. A relationship between x values, antisite disorder amounts and the growth temperature is established. The crystal chemical composition and stability, structural phase and antisite disorder amounts have been characterized by powder X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Electron Probe Micro Analysis/Wavelength Dispersive Spectroscopy (EPMA/WDS), Inductively Coupled Plasma/Atomic Emission Spectroscopy analysis (ICP/AES), coupled Thermo Gravimetric Analysis-Mass Spectrometry (TGA/MS) and magnetic susceptibility measurements. An unambiguous relationship between the c lattice parameter and the x value has been found.< Réduire

Mots clés en anglais

Growth from solutions

Single crystal growth

Inorganic compounds

Magnetic materials

DOI

http://dx.doi.org/10.1016/j.jcrysgro.2019.125372

Project ANR

Liquides de Spin Quantiques sur réseau Kagome - ANR-18-CE30-0022

Origine

Importé de hal

Unités de recherche

Institut de Chimie de la Matière Condensée de Bordeaux (ICMCB) - UMR 5026