Aqueous solution growth at 200 °C and characterizations of pure, 17O- or D-based herbertsmithite ZnxCu4-x(OH)6Cl2 single crystals
| hal.structure.identifier | Science et Ingénierie des Matériaux et Procédés [SIMaP] | |
| dc.contributor.author | VELÁZQUEZ, Matias | |
| hal.structure.identifier | Laboratoire de Physique des Solides [LPS] | |
| dc.contributor.author | BERT, Fabrice | |
| hal.structure.identifier | Laboratoire de Physique des Solides [LPS] | |
| dc.contributor.author | MENDELS, Philippe | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DENUX, Dominique | |
| hal.structure.identifier | iLM - Luminescence [iLM - LUMINESCENCE] | |
| dc.contributor.author | VEBER, Philippe | |
| hal.structure.identifier | Plateforme Aquitaine de Caractérisation des Matériaux [PLACAMAT] | |
| dc.contributor.author | LAHAYE, Michel | |
| hal.structure.identifier | Plateforme Aquitaine de Caractérisation des Matériaux [PLACAMAT] | |
| dc.contributor.author | LABRUGÈRE, Christine | |
| dc.date.issued | 2020 | |
| dc.identifier.issn | 0022-0248 | |
| dc.description.abstractEn | The aqueous solution growth of mm-sized, pure, 17O- or D-enriched herbertsmithite ZnxCu4-x(OH)6Cl2 single crystals is presented. A relationship between x values, antisite disorder amounts and the growth temperature is established. The crystal chemical composition and stability, structural phase and antisite disorder amounts have been characterized by powder X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Electron Probe Micro Analysis/Wavelength Dispersive Spectroscopy (EPMA/WDS), Inductively Coupled Plasma/Atomic Emission Spectroscopy analysis (ICP/AES), coupled Thermo Gravimetric Analysis-Mass Spectrometry (TGA/MS) and magnetic susceptibility measurements. An unambiguous relationship between the c lattice parameter and the x value has been found. | |
| dc.description.sponsorship | Liquides de Spin Quantiques sur réseau Kagome - ANR-18-CE30-0022 | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Growth from solutions | |
| dc.subject.en | Single crystal growth | |
| dc.subject.en | Inorganic compounds | |
| dc.subject.en | Magnetic materials | |
| dc.title.en | Aqueous solution growth at 200 °C and characterizations of pure, 17O- or D-based herbertsmithite ZnxCu4-x(OH)6Cl2 single crystals | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.jcrysgro.2019.125372 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Journal of Crystal Growth | |
| bordeaux.page | 125372 (4 p.) | |
| bordeaux.volume | 531 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-02391965 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-02391965v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Journal%20of%20Crystal%20Growth&rft.date=2020&rft.volume=531&rft.spage=125372%20(4%20p.)&rft.epage=125372%20(4%20p.)&rft.eissn=0022-0248&rft.issn=0022-0248&rft.au=VEL%C3%81ZQUEZ,%20Matias&BERT,%20Fabrice&MENDELS,%20Philippe&DENUX,%20Dominique&VEBER,%20Philippe&rft.genre=article |
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