Aqueous solution growth at 200 °C and characterizations of pure, 17O- or D-based herbertsmithite ZnxCu4-x(OH)6Cl2 single crystals
Idioma
en
Article de revue
Este ítem está publicado en
Journal of Crystal Growth. 2020, vol. 531, p. 125372 (4 p.)
Elsevier
Resumen en inglés
The aqueous solution growth of mm-sized, pure, 17O- or D-enriched herbertsmithite ZnxCu4-x(OH)6Cl2 single crystals is presented. A relationship between x values, antisite disorder amounts and the growth temperature is ...Leer más >
The aqueous solution growth of mm-sized, pure, 17O- or D-enriched herbertsmithite ZnxCu4-x(OH)6Cl2 single crystals is presented. A relationship between x values, antisite disorder amounts and the growth temperature is established. The crystal chemical composition and stability, structural phase and antisite disorder amounts have been characterized by powder X-ray diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Electron Probe Micro Analysis/Wavelength Dispersive Spectroscopy (EPMA/WDS), Inductively Coupled Plasma/Atomic Emission Spectroscopy analysis (ICP/AES), coupled Thermo Gravimetric Analysis-Mass Spectrometry (TGA/MS) and magnetic susceptibility measurements. An unambiguous relationship between the c lattice parameter and the x value has been found.< Leer menos
Palabras clave en inglés
Growth from solutions
Single crystal growth
Inorganic compounds
Magnetic materials
Proyecto ANR
Liquides de Spin Quantiques sur réseau Kagome - ANR-18-CE30-0022
Orígen
Importado de HalCentros de investigación