The Zn polymorphic analogues of the [Fe(PM–PEA)2(NCS)2] spin-transition compound
Langue
en
Article de revue
Ce document a été publié dans
Inorganica Chimica Acta. 2008, vol. 361, n° 12-13, p. 3519-3524
Elsevier
Résumé en anglais
We have studied the peculiarities of complex [Zn(PM–PEA)2(NCS)2], which presents large void cavities. As powder it does not show solvent inclusion, while as single crystals we have evidenced the existence of various ...Lire la suite >
We have studied the peculiarities of complex [Zn(PM–PEA)2(NCS)2], which presents large void cavities. As powder it does not show solvent inclusion, while as single crystals we have evidenced the existence of various polymorphs, with and without solvent inclusion. These results are preliminary results for the comprehension of the behaviour of mixed [FexZn1−x(PM–PEA)2(NCS)2], where Zn has been used to decrease the cooperative interactions between Fe atoms and check the effects on the wide hysteresis reported for this compound.< Réduire
Mots clés en anglais
X-ray crystal structures
Polymorphism
Spin crossover
Origine
Importé de halUnités de recherche