The Zn polymorphic analogues of the [Fe(PM–PEA)2(NCS)2] spin-transition compound
Language
en
Article de revue
This item was published in
Inorganica Chimica Acta. 2008, vol. 361, n° 12-13, p. 3519-3524
Elsevier
English Abstract
We have studied the peculiarities of complex [Zn(PM–PEA)2(NCS)2], which presents large void cavities. As powder it does not show solvent inclusion, while as single crystals we have evidenced the existence of various ...Read more >
We have studied the peculiarities of complex [Zn(PM–PEA)2(NCS)2], which presents large void cavities. As powder it does not show solvent inclusion, while as single crystals we have evidenced the existence of various polymorphs, with and without solvent inclusion. These results are preliminary results for the comprehension of the behaviour of mixed [FexZn1−x(PM–PEA)2(NCS)2], where Zn has been used to decrease the cooperative interactions between Fe atoms and check the effects on the wide hysteresis reported for this compound.Read less <
English Keywords
X-ray crystal structures
Polymorphism
Spin crossover
Origin
Hal imported