LE GAC, Frédéric; GUIONNEAU, Philippe; LÉTARD, Jean-François; ROSA, Patrick

doi:10.1016/j.ica.2008.03.011

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LE GAC, Frédéric
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

GUIONNEAU, Philippe
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

LÉTARD, Jean-François
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]

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Inorganica Chimica Acta. 2008, vol. 361, n° 12-13, p. 3519-3524

Elsevier

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We have studied the peculiarities of complex [Zn(PM–PEA)2(NCS)2], which presents large void cavities. As powder it does not show solvent inclusion, while as single crystals we have evidenced the existence of various polymorphs, with and without solvent inclusion. These results are preliminary results for the comprehension of the behaviour of mixed [FexZn1−x(PM–PEA)2(NCS)2], where Zn has been used to decrease the cooperative interactions between Fe atoms and check the effects on the wide hysteresis reported for this compound.< Leer menos

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X-ray crystal structures

Polymorphism

Spin crossover

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The Zn polymorphic analogues of the [Fe(PM–PEA)2(NCS)2] spin-transition compound

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